Neutralization Calculator — Acid-Base Titration
Find the exact volume of base solution needed to neutralize an acid solution at the equivalence point. Enter the molarity and volume of the acid, the number of ionizable protons (equivalents), and the molarity and equivalents of the base.
mol/L
mL
mol/L
Volume of base solution needed to reach the equivalence point
- 1
Acid moles of equivalents
1 × 0.1 × (25 ÷ 1000) = 0.0025n_a × M_a × V_a(L) gives the total H⁺ equivalents that must be neutralised. - 2
Base volume required
0.0025 ÷ (1 × 0.1) × 1000 = 25
How does this calculator work?
At the equivalence point, n_a × M_a × V_a = n_b × M_b × V_b. Enter the acid's molarity, volume, and equivalents, plus the base molarity and equivalents, and the calculator solves for the base volume needed to reach complete neutralization. Equivalents account for polyprotic acids (H₂SO₄, n=2) and polybasic bases.
Formula
How this is calculated
At the equivalence point of an acid–base titration, moles of acid equivalents (H⁺) exactly equal moles of base equivalents (OH⁻). For a monoprotic acid like HCl reacting with a monobasic base like NaOH, one mole of acid requires one mole of base. For polyprotic or polybasic species, multiply by the number of ionisable protons (n): H₂SO₄ has n = 2, Ca(OH)₂ has n = 2, and so on. The fundamental equation is n_a × M_a × V_a = n_b × M_b × V_b, which rearranges to find any unknown given the other four values.
This calculator solves for V_b — the volume of base required — given the acid parameters and the base molarity. It also estimates the total solution volume at the equivalence point and the approximate salt concentration (moles of acid equivalents divided by total volume). The salt concentration assumes complete reaction and no volume change on mixing, which is a standard approximation for dilute solutions.
Important limitations: the result gives the stoichiometric equivalence point only; it does not predict the final pH (which depends on whether the salt formed is acidic, basic, or neutral). The model also assumes ideal solution behaviour, no side reactions, and that the listed equivalents correctly describe the ionisation of the specific acid and base you are using.
Frequently asked questions
Equivalents (n) is the number of acidic H⁺ ions a molecule can donate (for acids) or OH⁻ ions it can accept/donate (for bases). HCl and NaOH have n=1; H₂SO₄ and Ca(OH)₂ have n=2; H₃PO₄ has n=3 for complete neutralization.
pH at the equivalence point depends on the strength of the acid and base and the hydrolysis of the resulting salt — it requires Ka/Kb values and a separate calculation. This calculator focuses on the volume stoichiometry only.
Yes — just swap the roles. Enter the base's molarity and volume in the acid fields and the acid's molarity in the base field. The math is symmetric: the formula finds whichever volume achieves equal molar equivalents.
Also known as
TG we-Calculate Editorial Team. (2026). Neutralization Calculator — Acid-Base Titration [Online calculator]. TG we-Calculate. https://we-calculate.com/calculator/neutralization-calculator
TG we-Calculate Editorial Team. "Neutralization Calculator — Acid-Base Titration." TG we-Calculate. 2026. https://we-calculate.com/calculator/neutralization-calculator.
TG we-Calculate Editorial Team, "Neutralization Calculator — Acid-Base Titration," TG we-Calculate, 2026. [Online]. Available: https://we-calculate.com/calculator/neutralization-calculator
@misc{wecalculate_neutralization_calculator, title = {Neutralization Calculator — Acid-Base Titration}, author = {{TG we-Calculate Editorial Team}}, howpublished = {\url{https://we-calculate.com/calculator/neutralization-calculator}}, year = {2026}, note = {TG we-Calculate} }
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